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服务平台首页>协同创新>专家库>专家详情

郭勇(教授)

所属单位:中国科学院上海有机化学研究所

担任职务:副研究员

擅长领域:

联系方式:021-54925462 邮箱:登录后查看

教育背景:1992年-1996年,厦门大学,化学系,本科/学士;1996年-2001年,中国科学院上海有机化学研究所,博士/研究生,陈庆云(院士);2002年-2004年,日本冈山大学,自然科学研究科和工学部应用化学科,博士后,宇根山健治(KenjiUneyama)教授;2004年-2006年,日本冈山理科大学,高技术研究中心HTRC,博士后,村桥俊一(Shun-IchiMurahashi)教授;2006年-2010年,美国爱达荷大学,化学系,博士后,Jean´neM.Shreeve教授。工作经历:2010年-至今,中国科学院上海有机化学研究所,有机氟化学重点实验室,研究生导师。有机氟化学

主要成就

{"awards": " ", "lunzhu": " 1.Hu, H.; Huang, Y.; Guo, Y. “Henry reaction of fluorinated nitro compounds,” Journal of Fluorine Chemistry, 2012, 133, 108-114.2.Guo, C.; Wang R.-W.; Guo, Y.; Qing, F.-L. “Palladium-catalyzed direct α-arylation of α-fluoroketones: A straightforward route to α-fluoro-α-arylketones,” Journal of Fluorine Chemistry, 2012, 133, 86-96.3.Wang, W; Chen, Q.-Y.; Guo, Y. “TiCl4-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center,” Synlett, 2011, 2705-2708.4.Lu, X.-Q.; Guo, Y.; Chen, Q.-Y. “Efficient Synthesis of meso-meso Linked Diporphyrins by Ni(0)-mediated Ullmann Homocoupling,” Synlett, 2011, 77-80.5.Guo, Y.; Tao, G.-H.; Blumenfeld, A.; Shreeve, J. M. “Impact of Silyl Enol Ether Stability on Palladium-catalyzed Arylations,” Organometallics, 2010, 29, 1818-1823.6.Guo, Y.; Tao, G.-H.; Zeng, Z.; Gao, H.; Shreeve,J.M.“Energetic Salts Based on Monoanions of N,N-bis[1H-Tetrazol-5-yl]amine and 5,5’-Bis(tetrazole),” Chemistry - A European Journal, 2010, 16, 3753-3762.7.Wang, R.; Xu, H.; Guo, Y.; Sa, R.; Shreeve, J. M. “Bis[3-(5-nitroimino-1,2,4-triazolate)-based Energetic Salts: Synthesis and Promising Properties of a New Family of High Density Insensitive Materials,” Journal of the American Chemical Society, 2010, 132, 11904-11905.8.Zhang, Y.; Guo, Y.; Joo, Y-H.; Parrish, D. A.; Shreeve, J. M. 3,4,5-Trinitropyrazole-based Energetic Salts, Chemistry – A European Journal, 2010, 16, 10778-10784.9.Tao, G.-H.; Guo, Y.; Parrish, D. A.; Shreeve, J. M. “Energetic 1,5-Diamino-4H-tetrazolium Nitro-substituted Azolates,” Jounral of Materials Chemistry, 2010, 20, 2999-3005.10.Wang, R.; Guo, Y.; Sa, R.; Shreeve, J. M. “Nitroguanidine-fused bicyclic guanidinium salts: A family of high density energetic materials,” Chemistry – A European Journal, 2010, 16, 8522-8529.11.Zhang, Y.; Gao, H.; Guo, Y.; Joo, Y.-H.; Shreeve, J. M. “Hypergolic N,N-Dimethylhydrozimiun Ionic Liquids,” Chemistry – A European Journal, 2010, 16, 3114-3120.12.Guo, Y.; Tao, G.-H., Joo, Y.-H., Wang, R.; Twanley, B.; Parrish, D. A.; Shreeve, J. M. “Impact Insensitive Dianionic Dinitrourea Salts: The CN4O52- Anion Paired with Nitrogen-Rich Cations,” Energy&Fuels, 2009, 23, 4567−4574.13.Guo,Y.; Zhao X.; Zhang, D.; Murahashi, S.−I. “Iridium−Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3−H Bond Activation a-to the Trifluoromethyl Group,” Angewandte Chemie, 2009, 121, 2081-2083; Angewandte Chemie Internation Edition, 2009, 48, 2047−2049.14.Guo, Y.; Twamley, B.; Shreeve J. M. “Pd−Catalyzed Arylation of Silyl Enol Ethers of Substituted a−Fluoroketones,” Organic & Biomolecular Chemistry, 2009, 1716−1722.15.Zeng, Z.; Guo, Y. Twamley, B.; Shreeve, J. M. “Energetic Polyazole Polynitrobenzenes and Their Coordination Complexes,” Chemical Communications, 2009, 6014−6016.16.Wang, R.; Guo, Y.; Zeng, Z.; Shreeve, J. M. “Nitrogen−rich Nitroguanidine-functionalized Tetrazolate Energetic Salts,” Chemical Communications, 2009, 2697-2699.17.Wang, R.; Guo, Y.; Zeng, Z.; Parrish, D. A.; Twamley, B.; Shreeve, J. M. “Furazan−functionalized Tetrazolate−based Salts: A New Family of Insensitive Energetic Materials,” Chemistry – A European Journal, 2009, 15, 2625−2634.18.Tao, G.−H.; Guo, Y.; Joo, Y.−H; Twamley, B.; Shreeve J. M. “Energetic Nitrogen−rich Salts and Ionic Liquids: 5−Aminotetrazole (AT) as a Weak Acid,” Journal of Materials Chemistry, 2008, 18, 5524–5530.19.Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K. “Selective Defluorination Approach to N−Cbz−3,3−difluoro−2−difluoromethylenepyrrole and its Application to 3,3−Difluoroproline Dipeptide Synthesis,” Journal of Organic Chemistry, 2007, 72, 8523−8526.20.Guo, Y.; Shreeve, J. M. “Effect of Fluorine on Palladium−catalyzed Cross−coupling Reactions of Aryl Bromides with Trifluoromethyl Aryl Ketones via Difluoroenol Silyl or Monofluoroenol Silyl Ethers,” Chemical Communications, 2007, 3583−3585.21.Guo, Y.; Gao, H.; Twamley, B.; Shreeve, J. M. “Energetic Nitrogen Rich Salts of N, N−bis[1(2)H−tetrazol−5−yl]amine,” Advanced Materials, 2007, 19, 2884−2888.22.Guo, Y.; Shreeve, J. M. “Difluoromethylene Compounds as Precursors to Ketones, Carboxylic Acids, Esters, Amides and Carbonates,” Journal of Fluorine Chemistry, 2007, 128, 1280−1285.23.Guo, Y.; Fujiwara, K.; Uneyama, K. “A Novel Route to Dipeptides via Noncondensation of Amino Acids: 2−Aminoperfluoropropene as a Synthon for Trifluoroalanine Dipeptides,” Organic Letters, 2006, 8, 827−829.24.Xiao, J.−C.; Duan, J.−X.; Li, A.−R.; Guo, Y.; Chen Q.−Y. “A Simple Method for Preparing Difluorodiodomethane from Difluoro(fluorosulfonyl)acetyl Fluoride,” Collection of Czechoslovak Chemical Communications, 2002, 67, 1320−1324.25.Guo, Y.; Chen, Q.−Y. “Iododifluoromethyl Alkenes [ICF2CH=CHR]: a Labile System Generated from 1,1−Difluoro−1,3−Diiodoalkanes and its Trapping with Nucleophiles,” Journal of Fluorine Chemistry, 2001, 107, 89−96.26.Guo, Y.; Chen. Q.-Y “The Reaction and its Product Conversion of Diflourodiiodomethane with Ethyl Vinyl Ether,” Acta Chimica Sinica 《化学学报》, 2001, 59, 1722-1729.27.Guo, Y.; Chen. Q.-Y “The Electron Transfer Reactions of 1,3-Diiodohexafluoropropane,” Acta Chimica Sinica《化学学报》, 2001, 59, 1730-1734.28.Guo, Y.; Chen, Q.−Y. “The Reactions of Difluorodiiodomethane with Nucleophiles,” Journal of Fluorine Chemistry, 2000, 102, 105−109.会议论文Uneyama, K.; Guo, Y.; Fujiwara, K.; Komatsu, Y. “A Novel Strategy for the Synthesis of Trifluoroalanine Oligopeptides,” Current Fluoroorganic Chemistry, 2007, ACS Symposium Series 949, Chapter 29, 462-476. "}