主要成就
{"awards": "
2012 年 上海市优秀毕业生 2012 年 中国科学院院长优秀奖
", "lunzhu": "
1. Xu, Z.; Liu, C.; Zhao, S.; Chen, S.; Zhao, Y. Molecular Sensors for NMR-Based Detection. Chem. Rev. 2018, acs.chemrev.8b00202. Invited 2. Zhao, Y.; He, Y.; Swager, T. M. Porous Organic Polymers via Ring Opening Metathesis Polymerization. ACS Macro Lett. 2018, 7, 300–304. 3. Zhao, Y.; Rocha, S. V.; Swager, T. M. Mechanochemical Synthesis of Extended Iptycenes. J. Am. Chem. Soc. 2016, 138, 13834-13837. 4. Zhao, Y.; Chen, L.; Swager, T. M. Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation. Angew. Chem., Int. Ed. 2016, 55, 917-921. 5. Zhao, Y.; Jiang, F.; Hu, J. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. J. Am. Chem. Soc. 2015, 137. 5199-5203. Highlighted in JACS Spotlights and Chem-Station 6. Zhao, Y.; Swager, T. M. Simultaneous Chirality Sensing of Multiple Amines by 19F NMR. J. Am. Chem. Soc. 2015, 137, 3221-3224. Highlighted in C&E News, JACS Spotlights, Chemistry Views, and Chem-Station 7. Zhao, Y.; Markopoulos, G.; Swager, T. M. 19F NMR Fingerprints: Identification of Neutral Organic Compounds in a Molecular Container. J. Am. Chem. Soc. 2014, 136, 10683-10690. Highlighted in “In the Pipeline” 8. Zhao, Y.; Swager, T. M. Detection and Differentiation of Neutral Organic Compound by 19F NMR with a Tungsten Calix[4]arene Imido Complex. J. Am. Chem. Soc. 2013, 135, 18770-18773. 9. Zhao, Y.; Ni, C.; Jiang, F.; Gao, B.; Shen, X.; Hu, J. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. ACS Catal. 2013, 3, 631-634. 10. Zhao, Y.; Gao, B.; Ni, C.; Hu, J. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. Org. Lett. 2012, 14, 6080-6083. Highlighted in Synfacts 11. Zhao, Y.; Bing, G.; Hu, J. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and bromodifluoromethylation of Carbonyl Compounds. J. Am. Chem. Soc. 2012, 134, 5790-5793. 12. Zhao, Y.; Hu, J., Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. Angew. Chem., Int. Ed. 2012, 51, 1033-1036. 13. Zhao, Y.; Huang, W.; Zheng, J.; Hu, J., Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature. Org. Lett. 2011, 13, 5342-5345. Highlighted in Synfacts Me3SiCF2H is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/21910464 14. Zhao, Y.; Huang, W.; Zhu, L.; Hu, J., Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. Org. Lett. 2010, 12, 1444-1447. Difluoromethyl 2-Pyridyl Sulfone is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/20210302
"}