主要成就
{"awards": "
", "lunzhu": "
1. Yu, Jiao; Lin, Jin-Hong*; Xiao, Ji-Chang* “Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines” Angew. Chem. Int. Ed. 2017, 56, 16669-16673. 2. Luo, Jia-Jia; Zhang, Min; Lin, Jin-Hong; Xiao, Ji-Chang* “Difluorocarbene for dehydroxytrifluoromethylthiolation of alcohols” J. Org. Chem. 2017, 82, 11206-11211. 3. Huang, Qiu-xia; Zheng, Qu-tong; Duan, Yaya; Lin, Jin-Hong*; Xiao, Ji-Chang*; Zheng, Xing* “Diastereoselective Synthesis of CF3-Containing Vicinal Diamines” J. Org. Chem. 2017, 82, 8273-8281. 4. Duan, Yaya; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X-H bonds (X = Si, C, P)” Org. Chem. Front. 2017, 4, 1917-1920. 5. Duan, Yaya; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “Difluoromethylcarbene for iron-catalyzed cyclopropanation” Chem. Commun. 2017, 53, 3870-3873. 6. Zheng, Jian; Cheng, Ran; Lin, Jin-Hong; Yu, Dong-Hai; Ma, Longle; Jia, Lina; Zhang, Lan; Wang, Lu; Xiao, Ji-Chang*; Liang, Steven H.* “An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of 18F-Labeled α-SCF3 Carbonyl Compounds” Angew. Chem. Int. Ed. 2017, 56, 3196-3200. 7. Deng, Zuyong; Liu, Can; Zeng, Xian-Liang; Lin, Jin-Hong*; Xiao, Ji-Chang* “Nucleophilic 1,1-Difluoroethylation with Fluorinated Phosphonium Salt” J. Org. Chem. 2016, 81, 12084-12090. 8. Deng, Xiao-Yun; Lin, Jin-Hong; Xiao, Ji-Chang* “Pd-Catalyzed Transfer of Difluorocarbene” Org. Lett. 2016, 18, 4384-4387. 9. Deng, Zuyong; Lin, Jin-Hong; Cai, Ji; Xiao, Ji-Chang* “Direct Nucleophilic Difluoromethylation of Carbonyl Compounds” Org. Lett. 2016, 18, 3206-3209. 10. Duan, Yaya; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “A Trifluoromethylcarbene Source” Org. Lett. 2016, 18, 2471-2474. 11. Ji, Yun-Long; Luo, Jia-Jia; Lin, Jin-Hong; Xiao, Ji-Chang*; Gu, Yu-Cheng “Cu-catalyzed C-H trifluoromethylation of 3-arylprop-1-ynes for the selective construction of allenic Csp2-CF3 and propargyl Csp3-CF3 bonds” Org. Lett. 2016, 18, 1000-1003. 12. Deng, Zuyong; Lin, Jin-Hong; Xiao, Ji-Chang* “Nucleophilic arylation with tetraarylphosphonium salts” Nat. Commun. 2016, 7: 10337 doi: 10.1038/ncomms10337. 13. Zheng, Jian; Lin, Jin-Hong; Yu, Liu-Ying; Wei, Yun; Zheng, Xing; Xiao, Ji-Chang* “Cross-Coupling between difluorocarbene and carbene-derived in-termediates generated from diazocompounds for the synthesis of gem-difluoroolefins” Org. Lett. 2015, 17, 6150-6153. 14. Zheng, Jian; Wang, Lu; Lin, Jin-Hong; Xiao, Ji-Chang*; Liang, Steven H.* “Difluorocarbene-Derived Trifluoromethylthiolation and [18F]Trifluoromethylthiolation of Aliphatic Electrophiles” Angew. Chem. Int. Ed. 2015, 54, 13236-13240. 15. Duan, Yaya; Zhou, Bin; Lin, Jin-Hong; Xiao, Ji-Chang* “Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation” Chem. Commun. 2015, 51, 13127-13130. 16. Deng, Xiao-Yun; Lin, Jin-Hong; Zheng, Jian; Xiao, Ji-Chang* “Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation” Chem. Commun. 2015, 51, 8805-8808. 17. Zheng, Jian; Lin, Jin-Hong; Deng, Xiao-Yun; Xiao, Ji-Chang* “1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation” Org. Lett. 2015, 17, 532-535. 18. Ji, Yun-Long; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-Cheng. “Copper-catalyzed Tandem Trifluoromethylation/ Cyclization of Internal Alkynes” Org. Chem. Front. 2014, 1, 1280-1284. 19. Yang, Tang-Po; Li, Qiang; Lin, Jin-Hong; Xiao, Ji-Chang*. “Boron-trihalide-promoted Regioselective Ring-opening Reactions of gem-Difluorocyclopropyl Ketones” Chem. Commun. 2014, 50, 1077-1079. 20. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong; Xiao, Ji-Chang*; Gu, Yu-Cheng. “Difluoromethylation and Trifluoromethylation Reagents Derived from Tetrafluoroethane β-Sultone: Synthesis, Reactivity and Applications” Coord. Chem. Rev. 2014, 261, 28-72. 21. Zheng, Jian; Lin, Jin-Hong; Cai, Ji; Xiao, Ji-Chang*. “Conversion between Difluorocarbene and Difluoromethylene Ylide” Chem. Eur. J. 2013, 19, 15261-15266. 22. Yang, Tang-Po; Lin, Jin-Hong; Chen, Qing-Yun; Xiao, Ji-Chang*. “A novel reaction of gem-difluorocyclopropyl ketones with nitriles leading to 2-fluoropyrroles” Chem. Commun. 2013, 49, 9833-9835. 23. Zheng, Jian; Cai, Ji; Lin, Jin-Hong; Guo, Yong; Xiao, Ji-Chang*. “Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine” Chem. Commun. 2013, 49, 7513-7515. 24. Lin, Jin-Hong; Zong, Guoqiang; Du, Ruo-Bing; Xiao, Ji-Chang*; Liu, Shubin*. “The asymmetric synthesis of CF3- or -CF2-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst” Chem. Commun. 2012, 48, 7738-7740. 25. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system” Chem. Soc. Rev. 2012, 41, 4536-4559. 26. Hao, Fei; Jiang, Hua–Wei; Zong, Guoqiang; Zhou, Zhiguo; Du, Ruo–Bing; Chen, Qing–Yun; Xiao, Ji–Chang*. “Electrophilic Fluoroalkylation of Ni(II) N-Confused Porphyrins with Fluoroalkylarylsulfonium Salts” J. Org. Chem. 2012, 77, 3604-3608. 27. Zhang, Cheng-Pan; Cai, Ji; Zhou, Chang-Bing; Wang, Xiao-Ping; Zheng, Xing; Gu, Yu-Cheng; Xiao, Ji-Chang*. “Copper-Mediated Trifluoromethylation of Arylboronic Acids by Trifluoromethyl Sulfonium Salts” Chem. Commun. 2011, 47, 9516-9518. 28. Zhu, Zhi-Qiang; Zheng, Xing-Liang; Jiang, Ning-Fei; Wan, Xiaolong; Xiao, Ji-Chang*. “Chiral N-Heterocyclic Carbene Catalyzed Annulation of α,β-Unsaturated Aldehydes with 1,3-Dicarbonyls” Chem. Commun. 2011, 47, 8670-8672. 29. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang*. “Generation of the CF3 Radical from Trifluoromethylsulfonium Triflate and its Trifluoromethylation of Styrenes” Chem. Commun. 2011, 47, 6632-6634. 30. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang*. “Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts” Angew. Chem. Int. Ed. 2011, 50, 1896-1900. 31. Zhang, He; Zhou, Chang-Bing; Chen, Qing-Yun; Xiao, Ji-Chang*; Hong, Ran*. “Monofluorovinyl Tosylate: A Useful Building Block for the Synthesis of Terminal Vinyl Monofluorides via Suzuki-Miyaura Coupling” Org. Lett., 2011, 13, 560–563. 32. Zhu, Zhi-Qiang; Xiao, Ji-Chang*. “N-Heterocyclic Carbene Catalyzed Reaction of Alkynyl Aldehydes with 1,3-Ketoesters or 1,3-Diketones” Adv. Synth. Catal. 2010, 352, 2455-2458. 33. Jiang, Hua-Wei; Hao, Fei; Chen, Qing-Yun; Xiao, Ji-Chang*; Liu, Shu-Bin; Gu, Yu-Cheng. “Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols” J. Org. Chem. 2010, 75, 3511-3514. 34. Lin, Jin-Hong; Zhang, Cheng-Pan; Xiao, Ji-Chang*. “Enantioselective aldol reaction of cyclic ketones with aryl aldehydes catalyzed by a cyclohexanediamine derived salt in the presence of water” Green Chem. 2009, 11, 1750-1753. 35. Jiang, Hua-Wei; Chen, Qing-Yun; Xiao, Ji-Chang*; Gu, Yu-Cheng. “The Oxidation of Ni(II) N-Confused Porphyrins (NCPs) with Azo Radical Initiators and an Unexpected Intramolecular Nucleophilic Substitution Reaction via a Proposed Ni(III) NCP Intermediate” Chem. Commun. 2009, 3732-3734. 36. Jiang, Hua-Wei; Chen, Qing-Yun; Xiao, Ji-Chang*; Gu, Yu-Cheng. “Synthesis and Reactions of the First Fluoroalkylated Ni(II) N-Confused Porphyrins” Chem. Commun. 2008, 5435-5437. 37. Hang, Xiao-Chun; Chen, Qing-Yun; Xiao, Ji-Chang*. “Ring-Opening Reactions of Difluoro(methylene)cyclopropanes with Halogens and Amines” J. Org. Chem. 2008, 73, 8598-8600. 38. Zhu, Zhi-Qiang; Xiang, Shaoji; Chen, Qing-Yun; Chen, Chaosen; Zeng, Zhuo; Cui, Yi-Ping*; Xiao, Ji-Chang*. “Novel low-melting salts with donor-acceptor substituents as targets for second-order nonlinear optical applications” Chem. Commun. 2008, 5016-5018.
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